| State Deputy | Council | Period |
| William J. O'Brien | 205 | 1889 - 1900 |
| Harry S. Cox | 205 | 1900 - 1902 |
| Joseph G. Coale | 370 | 1902 - 1903 |
| Edward T. Clifford | 370 | 1903 - 1905 |
| William H. Gahan | 205 | 1905 - 1907 |
| Charles W. Heuisler | 370 | 1907 - 1908 |
| Philip C. Mueller | 205 | 1908 - 1913 |
| Francis A. Wolfhope | 586 | 1913 - 1915 |
| Edgar N. Ganster - biography | 370 | 1915 - 1918 |
| John Trainor | 205 | 1918 - 1920 |
| William S. Aumen, Former Master | 370 | 1920 - 1923 |
| Isaac S. George | 205 | 1923 - 1925 |
| George R. Callis, Jr. | 1960 | 1925 - 1927 |
| Walter E. Kennedy | 205 | 1927 - 1929 |
| Bernard J. Flynn | 370 | 1929 - 1931 |
| Leo D. Ward, Former Master | 370 | 1931 - 1934 |
| W. Victor Maconachy, Former Master | 205 | 1934 - 1937 |
| John A. Flanigan, Former Supreme Director | 205 | 1937 - 1940 |
| Joseph G. Loeffler | 1733 | 1940 - 1943 |
| Lewis A. List - biography | 1960 | 1943 - 1946 |
| Frank A. Shallenberger | 205 | 1946 - 1949 |
| John J. Schwarz | 370 | 1949 - 1951 |
| Charles W. Bucy | 2797 | 1951 - 1953 |
| John P. Bauernschub, Former Vice Supreme Master | 370 | 1953 - 1955 |
| Charles B. Humelsine, Former Supreme Director - biography | 1365 | 1955 - 1960 |
| John H. Griffin, M.D., Former Supreme Physician - biography | 2293 | 1960 |
| Maurice J. Klein - biography | 2901 | 1960 - 1963 |
| Francis G. McFarland, Former Master - biography | 370 | 1963 - 1966 |
| M. D. Gilligan, DDS, Fomer Master - biography | 1393 | 1966 - 1968 |
| Frank J. Heiner, Jr., Former Master - biography | 370 | 1968 - 1970 |
| Charles H. Zeunges | 1733 | 1970 - 1972 |
| Michael J. Sierco - biography | 2577 | 1972 - 1974 |
| Go in Peace to Love and Serve the Lord" | ||
| Charles I. Reese - biography | 205 | 1974 - 1976 |
| George W. Lovenstein | 586 | 1976 - 1977 |
| F. Eugene Hogan | 2797 | 1977 - 1978 |
| "I Am My Brother's Keeper" | ||
| William B. Clayton, Jr. - biography | 2901 | 1978 - 1980 |
| "Let Charity and Love Prevail" | ||
| Bernard J. Zeller, Sr. - biography | 2521 | 1980 - 1982 |
| "Come and Follow Me" | ||
| Joseph A. Sauro | 5547 | 1982 - 1984 |
| "Because We Care" | ||
| Richard C. Bumsted | 2521 | 1984 - 1986 |
| "One Family Under God - Reaching Out" | ||
| Aldo G. Bartolomei - biography | 2577 | 1986 - 1988 |
| "Lord, Make Me An Instrument of Your Peace" | ||
| Andrew C. Bauer, Former Master | 2942 | 1988 - 1990 |
| "Lord, Let Your Light Shine Through Us" | ||
| James Olivarri | 2169 | 1990 - 1992 |
| "Together as One" | ||
| Francis M. Feeley, Former Vice Supreme Master | 205 | 1992 - 1994 |
| "Loving, Caring, Sharing" | ||
| John J. Glynn | 4076 | 1994 - 1996 |
| "Come Share Your Gifts" | ||
| John R. Albright, Former Master | 4076 | 1996 - 1998 |
| "Proclaim the Gospel of Life" | ||
| Philip L. Asplen, Jr., Former Master | 2521 | 1998 - 2000 |
| "We Are His Hands" | ||
| Romeo Gauthier | 9127 | 2000 - 2002 |
| "Making a Difference in People's Lives" | ||
| Richard L. Sherbert, Jr. | 6793 | 2002 - 2004 |
| "First, Charity" | ||
| Ronald B. White, Supreme Director | 7612 | 2004 - 2006 |
| "It is giving that we receive..." | ||
| Edgar D. Haynes, KCHS, Immediate Past State Deputy, Former Master | 11715 | 2006 - 2008 |
| "Living Our Faith" |